Compositional variations in biomass modify composition and yield of pyrolysis oil. After pyrolysis, characterization of the products with an emphasis on the biooil and the biochar was performed using various approaches including karl fischer watercontent tests, ftir, sem, tga and cnho analyses. Institute for advanced studies university of sao paulo, brazil. In the study, bio oils from fast pyrolysis of west african cordia cm and. Product yields from slow pyrolysis are approximately 35% biochar, 30% bio oil, and 35% gaseous products. So, the main data here presented, are concerning the pyrolysis of tyres or rubber works presenting similar composition and properties. Also, an exergetic analysis of the pyrolysis reactor was performed to study the performance. Oct 17, 2011 appropriate technology graduate students at appalachian state university in boone, nc demonstrate the pyrolysis of biomass in an airless system. Define a new biooil specification inside or outside of d396 fuel product is so low in oxygen content it is considered a hydrocarbon and so is equivalent to no. Brown iowa state university and jennifer holmgren uop. For the bio oil plant technical and economic analysis, the process is based on fast pyrolysis, which is composed of five major processing areas. Furnace oil is a fuel oil that can be burned in an atomizing burner and that is usually a distilled product having a. Lifecycle assessment of pyrolysis biooil production philip steele maureen e. University of groningen pyrolysis oil upgrading to.
Effect of heating rate the heating rates in this study were varied as follows. Tg, dtg and dsc curves of biooil pyrolysisgasification 20c min. The pyrolyze biooils can be directly used as fuels in boilers or subsequently upgraded to produce fuels and bulk chemicals using several methods such as zeolite cracking,, hydrogenation,, and aqueous phase processing. Boateng eastern regional research center, agricultural research service, u. Characterization, stability analysis, and catalytic upgrading to fuels and chemicals a dissertation presented by tushar p. Distributed fast pyrolysis for conversion of biomass to. Revised manuscript received march 3, 2008 biooils from the fast pyrolysis of switchgrass. Fast pyrolysis biooil technology and production the presentation herein is intended for presentation purposes and contains confidential information. Investigation of biomass pyrolysis on noncatalytic process. Pyrolysis is the thermal decomposition of biomass occurring in the absence of oxygen. Production of renewable commodity chemicals from biooil derived from fast pyrolysis of biomass has received considerable interests, but hindered by the presence of. Characterization, stability analysis, and catalytic upgrading to fuels and chemicals.
Investigation of biomass pyrolysis on noncatalytic. Pyrolysis oil upgrading to transportation fuels by catalytic hydrotreatment. Jan 24, 20 production of renewable commodity chemicals from bio oil derived from fast pyrolysis of biomass has received considerable interests, but hindered by the presence of innumerable components in bio oil. The blending of pyrolysis oil and dee are mixed with diesel fuel with its volume. The products of biomass pyrolysis include biochar, bio oil and gases including methane, hydrogen, carbon monoxide, and carbon dioxide. Temperature and the heating rate has a positive correlation with the biooil yield. Biooil hydrocracking directly converts biomass into liquid biooil lignin, carbohydrate derivatives, and water and char biooil catalytically converted into hydrocarbon fuel green diesel pyrolyzer carbohydrate derived aqueous phase biooil recovery phase separation steam reformer hydrocracker fibrous biomass biooil vapor hydrogen. For the biooil plant technical and economic analysis, the process is based on fast pyrolysis. After pyrolysis, characterization of the products with an emphasis on the bio oil and the bio char was performed using various approaches including karl fischer watercontent tests, ftir, sem, tga and cnho analyses.
As a matter of fact, numerous letters have had no reply or. Cooper abstract as part of the consortium for research on renewable industrial materials phase i lifecycle assessments of biofuels, life. The oil produced has very high quality and close to the commercial petroleum derived liquid fuels. Astm d7544 standard for pyrolysis liquid biofuel not applicable two options. International journal of recent technology and engineering ijrte. The pyrolysis and oxidation reactions of sludge pyrolytic oil are also investigated using thermogravimetric analysis. Jun 15, 2015 in the case of development and utilization of biooils, a quantitative chemical characterization is necessary to evaluate its actual desired characteristics for downstream production. The topic summarized about biomass like sawdust that could be a good renewable energy source in order to satisfy the demand up to. Boateng the science and engineering for a biobased industry wyndmoor, pa august 3, 2010. Pyrolysis oil, sometimes also known as biocrude or biooil, is a synthetic fuel under investigation as substitute for petroleum. The products of biomass pyrolysis include biochar, biooil and gases including methane, hydrogen, carbon monoxide, and carbon dioxide.
This report also provides the basis for cost target projections through. Recent developments in biomass pyrolysis for biofuel production. Chemical composition of biooils produced by fast pyrolysis. Production of liquid fuels from waste lube oils used by. Hc value represent a more valuable source of energy for pyrolysis oils than biomass. A technology nreltp51037779 november 2006 assessment and economic analysis m.
Chemical composition of biooils produced by fast pyrolysis of two energy crops charles a. Vispute submitted to the graduate school of the university of massachusetts amherst in partial fulfillment of the requirements for the degree of doctor of philosophy february 2011 chemical engineering. Institute for advanced studies university of sao paulo, brazil robert c. Product yields from slow pyrolysis are approximately 35% biochar, 30% biooil, and 35% gaseous products. Oil derived from tire rubber pyrolysis contains high sulfur content, which gives it high potential as a pollutant and should be desulfurized.
Fast pyrolysis converts 60 wt% of lignocellulosic materials into bio oil. For the pyrolysis bio oil prepared from tl, the content of heterocyclic compounds decreased with an increase in temperature, i. In addition to these valuable building blocks, pyrolysis oil can be processed into traditional petrochemicals and. Lifecycle assessment of pyrolysis biooil production. The enquiry has been operated by writing, visiting, and bibliographical means. Primarily to produce char through carbonization utilizes low temperatures around 400. General biomass processing pyrolysis different kinds of pyrolysis emphasis on fast pyrolysis biooil properties description of fast pyrolysis mechanisms of fast pyrolysis. Fast pyrolysis is a thermal oxygenlimited conversion involving a rapid. Production of gasoline and diesel from biomass via fast pyrolysis, hydrotreating, and. Developing a model to predict the oil quantity from pyrolysis of plastic waste seems less complex than the pyrolysis of wood biomass. Pyrolysis oils and waste plastic are studied to apply with one cylinder multipurpose agriculture diesel engine. Sep 01, 2015 waste tyre pyrolysis plant henan doing produced wste tyre pyrolysis plant can convert waste tyreplasticrubber to pyrolysis oil. Fast pyrolysis rapid thermal decomposition of organic compounds in the absence of oxygen to produce liquids, char, and gas dry feedstock.
Pyrolysis is the thermal decomposition of materials at elevated temperatures in an inert atmosphere. Fast pyrolysis biooils from wood and agricultural residues. Fast pyrolysis liquid is a potential source of revenues for companies who have biomass residues at their disposal. In addition to these valuable building blocks, pyrolysis oil can be processed into traditional petrochemicals and plastic intermediates through refining and processing. Recent developments in biomass pyrolysis for biofuel. In 20, mullen and two other research erslead scientist akwasi boateng and newand more economicalpyrolysis techniques for biooil. Fast pyrolysis bio oil pyrolysis liquid from plant residues is one alternative to replace fossil fuels and feedstocks. Pdf fuel oil quality and combustion of fast pyrolysis. Pyrolysis is most commonly used in the treatment of organic materials. Coke deposition bed plugging deactivation tos 100 hrs. What is the difference between pyrolysis oil and furnace oil.
The yield prediction of synthetic fuel production from pyrolysis of. Pdf chemical composition of biooils produced by fast. Frontiers estimation and comparison of biooil components. In the study, biooils from fast pyrolysis of west african cordia cm and. Slow pyrolysis solid char product via torrefaction or carbonization. This study explored on biofuels production from pyrolysis of nannochloropsis oculata and subsequent biooil upgrading by fractional distillation and zeolite upgrading. A simple pyrolysis reactor system has been used to pyrolyse waste hdpe with the.
The results showed that the pyrolysis of palm oil wastes yielded more biooil than biochar or noncondensable gases. Distributed fast pyrolysis for conversion of biomass to stable refinablecrude bio. The pyrolysis bio oils have heating values of 4050% of that of petroleum fuels. C over a long period of time to maximize char formation. And on this basis, new explorations in the field of influence. From that we can summarized that the slow pyrolysis is practically less efficient in terms of bio oil. Characterization of biooil and biochar from pyrolysis of.
Liquefaction of biomass by fast pyrolysis and subsequent upgrading of the resulting pyrolysis oil biooil by hydrotreating and hydrocrackingrefinery processes that use hydrogen to remove. Considerable efforts have been made to convert wood biomass to liquid fuels and chemicals since the oil crisis in mid1970s. This presentation was a team work of 4 member presented to the faculties of the university of manchester. This paper describes an analytical approach for the determination of families of lightweight chemicals from biooils by using gcms techniques. Fast pyrolysis and biooil upgrading ascension publishing. Technical feasibility study on biofuels production from. Newand more economicalpyrolysis techniques for biooil.
Waste tyre pyrolysis plant henan doing produced wste tyre pyrolysis plant can convert waste tyreplasticrubber to pyrolysis oil. Pyrolysis oil from biomass fast pyrolysis key features pretreatment feedstock drying to less than 10% is necessary byproduct gas or char combustion can be employed feedstock grinding as small particle size i. Followup of the main changes in the chemical composition of a pine pyrolysis bio oil over one year of storage at various temperatures. The word is coined from the greekderived elements pyro fire and lysis separating. Pyrolytic oil or biooil is a kind of tar and normally contains levels of oxygen too high to be considered a hydrocarbon. An overview of catalysts in biomass pyrolysis for production of biofuels.
Largescale pyrolysis oil technical report production. Fast pyrolysis bio oil technology and production the presentation herein is intended for presentation purposes and contains confidential information. A box flow diagram for fast pyrolysis followed by catalytic bio oil upgrading to gasoline. It is obtained by heating dried biomass without oxygen in a reactor at a temperature of about 500 c with subsequent cooling.
The twostep bio oil hydrotreatment concept has had a major impact in the development of bio oil hydrotreatment. Hydrocracking the heavy portion of the stable hydrocarbon oil. Our first commercial scale 25 mw plant empyro in hengelo was opened in may 2015. Table 1 shows the type of biomass use in the production of biooil by various research work and the type of biomass obtain for this study. The main advantages of pyrolysis liquid fuels includes 28, 33. Wood chips, sugar cane bagasse, straw, sunflower husk, etc. Recent researches in environmental and geological sciences isbn. Pyrolysis oil contains carboxylic acids, and phenolic and nitrogen compounds, which can be converted into resins, adhesives, solvents, fertilizers, flavors and more. Biooil production pyrolysis free download as powerpoint presentation.
Pyrolysis bio oil pyrolysis bio oil is the liquid produced from the condensation of vapour of a pyrolysis reaction. Once produced, biooils may be shipped, stored, and utilized much like conventional liquid fuels once their specific fuel properties are taken into account. Appropriate technology graduate students at appalachian state university in boone, nc demonstrate the pyrolysis of biomass in an airless system. We kindly thank you for your interest in our fast pyrolysis technology, which converts many types of biomass into a homogeneous liquid called pyrolysis oil. State of the art of bio oil upgrading at the beginning of the project bio oil zone i stabilization zone ii. Mar 31, 2015 fast pyrolysis of biomass for biooil production. Technoeconomic analysis of biomass fast pyrolysis to. It is shown that the optimum temperature for waste tire pyrolysis in a rotary kiln reactor is around 450550oc. A comprehensive characterization of pyrolysis oil from. Hydrotreating the fast pyrolysis oil to create a stable hydrocarbon oil with less than 2 percent oxygen. The experience of design and operation of the semiscale plant will be helpful for building a commercial scale plant in the future.
Scahill nrel is operated by midwest research institute battelle contract no. The nuclear magnetic resonance results demonstrated. Pyrolysis is one of a number of possible paths for converting biomass to. This research describe a comparison of the use of pyrolysis oils which are the tire pyrolysis oil, plastic pyrolysis oil and diesel oil in the assessment of engine performance, and feasibility. Pdf a comparison of the use of pyrolysis oils in diesel. This study, pyrolysis technique is founded from recycling principle of used oil concept from. Mass production of chemicals from biomassderived oil by. The resulting pyrolysis oil or biooil can be obtained with yields up to 7080 wt. Pyrolysis, especially pyrolysis of coal, is an age. You are advised to consult the publishers version publishers pdf if you. Research and development in the fast pyrolysis of biomass has been absorbing substantial amounts of human and economic resources over the last two decades, resulting in notable advances in various areas including.
Testing, evaluation, and qualification of biooil for. Production of liquid fuels from waste lube oils used by pyrolysis process wisa manasomboonphan1, suwannee junyapoon1 1 department of chemistry, faculty of science, king mongkuts institute of technology ladkrabang, bangkok 10520, thailand abstract. Fast pyrolysis biooil pyrolysis liquid from plant residues is one alternative to replace fossil fuels and feedstocks. Testing, evaluation, and qualification of biooil for heating. Operating parameters for biooil production in biomass. Because of the difficulties of collect and the lowness of the individual stocks, other rubber waste have been neglected. It is the fundamental chemical reaction that is the precursor of both the combustion and gasification processes and occurs naturally in the first two seconds. Pyrolysis biooil is the liquid produced from the condensation of vapour of a pyrolysis reaction. Fast pyrolysis of biomass for biooil production youtube. What is the difference between pyrolysis oil and furnace. Therefore, the pyrolysis technology has very high energy profit, 42. Fast pyrolysis utilizes biomass to produce a product that is used both as an energy source and a feedstock for chemical production.
Pdf a comparison of the use of pyrolysis oils in diesel engine. Pyrolysis is one of the wellknown technologies used for bio oil production, where temperature, heating rate, and nitrogen flow rate are the crucial parameters governing its kinetics. Database constitutes a tool to optimize yields or explain the composition of the oil. Biooil yield and quality enhancement through fast pyrolysis and.